Similarities and differences between alkanes and alkenes

alkanes vs alkenes
SIMILARITIES:
  • Both are insoluble in water
  • Both are neutral
  • Both burn in excess air to produce carbon dioxide and water.

DIFFERENCES:
Alkanes:
  • General formula: CnH2n+2
  • Saturated hydrocarbon
  • Do not decolourise the purple acidified potassium manganate (VII) solution.
  • Do not decolourise the reddish-brown bromine solution.
  • Burn with a less sooty flame because the percentage by mass of carbon is lower than that of the corresponding alkenes. 

Alkenes
  • General formula: CnH2n
  • Unsaturated hydrocarbon
  • Decolourise the purple acidified potassium manganite (VII) solution.
  • Decolourise the reddish-brown bromine solution.
  • Burn with a more sooty flame because the percentage by mass of carbon is higher than that of the corresponding alkanes. 

SPM Form 5: Rate of reaction (Checklist)

  • Rate of reaction: The decrease in the amount of reactant used or the increase in the amount of product obtained in a given time. The rate of reaction measures how much product is formed in a certain time. Some reactions are slow, such as rusting, and some are fast, like burning.
  • Average of reaction: The average value of the rate of reaction within a specified period of time.
  • Rate of reaction at a given time: The actual rate of reaction at a specific time.
  • Collision theory: A model that explains reaction rate as the result of particles colliding with a certain minimum energy.
  • Effective collision: A collision in which the particles meet with sufficient energy and an orientation that allows them to react.
  • The rate of reaction decreases with the increase of time.
  • The rate of reaction increases as the total surface area of a solid reactant increases.
  • The rate of reaction increases as the concentration of reactant increases.
  • The rate of reaction increases as the temperature of a reactant increases.
  • The rate of reaction increases when a positive catalyst is used and the rate of reaction increases when the amount of a positive amount used increases.
  • Catalyst: A substance which alters the rate of a chemical reaction while it remains chemically unchanged at the end of the reaction. 

Soap vs Detergent: Similarities and Differences


Similarities:
  • Both are cleansing agents.
  • Each ion of both soap and detergent consists of a long chain of hydrocarbon part which is hydrophobic and an ionic part which is hydrophilic.
  • Both can reduce the surface tension of water, thus, allowing water to wet the surface.
  • The cleansing actions of both soap and detergent enable oil droplets to disperse in water and form an emulsion that will not redeposit on the surface.
  • Both are effective as cleansing agents in soft water.

Differences:
  • Soap is biodegradable while detergent is not biodegradable (can cause environmental pollution).
  • Detergent is an effective cleansing agent in hard water, soft water and in acidic solution but soap is only effective as a cleansing agent in soft water.

SPM Chemistry Form 4 and Form 5: Checklist (Definitions)

Form 4:

Form 5:

SPM Form 4: Salts (Checklist)

  • Salts: An ionic compound formed when the hydrogen ion in an acid is replaced by a metal ion or an ammonium ion. Salts are formed as the product of an acid reaction with an alkali. Soluble salts dissolve in water. Insoluble salts do not dissolve in water.
  • Recrystallization: A technique used to purify crystals of a soluble salt by carrying out the crystallization process again on these crystals.
  • Precipitation reaction: A reaction which involves the reaction between two aqueous reactants to form an insoluble substance.
  • Continuous variation method: An experiment which involves the reaction of a solution at fixed volume and another solution with volumes that varies uniformly.
  • All carbonate salts are decomposed on heating to liberate carbon dioxide gas, CO2 except sodium carbonate, Na2CO3 and potassium carbonate, K2CO3.
  • All nitrate salts are decomposed on heating to liberate nitrogen dioxide gas, NO2 and oxygen gas, O2 except sodium nitrate, NaNO3 and potassium nitrate, KNO3 which liberate oxygen gas, O2 only.
  • The presence of carbonate ions can be confirmed by adding dilute acids.
  • The presence of sulphate ions can be confirmed by adding acidified barium chloride, BaCl2 solution.
  • The presence of chloride ions can be confirmed by adding acidified silver nitrate, AgNO3 solution.
  • The presence of nitrate ions can be confirmed by adding dilute sulphuric acid, H2SO4 followed by iron (II) sulphate, FeSO4 solution and a little concentrated sulphuric acid, H2SO4.
  • The identify of cation can be determined by using sodium hydroxide, NaOH solution and ammonia, NH2 solution except aluminium ion, Al3+ and lead (II) ion, Pb2+.
  • Ammonium ion can be tested by heating with a strong alkali or adding Nessler’s reagent.
  • Iron (II) ion and iron (III) ion can be tested by using potassium hexacyanoferrate (II), K4Fe(CN)6 solution, potassium hexacyanoferrate (III), K3Fe(CN)6 or potassium thiocyanate, KSCN solution.
  • Lead (II) ions can be tested by using potassium iodide, KI solution.

SPM Form 4: Manufactured Substances in Industry (Checklist)

contact process
  • Sulphuric acid (H2SO4) is a highly corrosive acid made from sulfur dioxide; widely used in the chemical industry.
  • Contact process: the industrial process for making sulfuric acid.
  • Ammonia (NH3) is colorless, pungent gas composed of nitrogen and hydrogen.
  • Haber process: the process for making ammonia from nitrogen and hydrogen, in industry.
  • Ammonium fertilizer: A salt that is prepared from the reaction between ammonia and an acid. Ammonium sulphate, (NH4)2 SO4 which is an ammonium fertilizer can be prepared from the reaction between ammonia, NH3 solution and sulphuric acid, H2SO4.
  • Alloys: A mixture of two or more elements with certain fixed composition in which the major component is a metal. Alloy is harder than pure metal.
  • Metal corrosion: The gradual destruction of a metal by reaction with its environmental. Iron rusts faster than steel. Stainless steel does not rust.
  • Polymer: a compound containing very large molecules, formed by polymerization.
  • Synthetic polymers are derived from petroleum oil, and made by scientists and engineers. Examples of synthetic polymers include nylon, polyethylene, polyester, Teflon, and epoxy.
  • Natural polymers occur in nature and can be extracted and often water-based. Examples of naturally occurring polymers are silk, wool, DNA, cellulose and proteins.
  • Glass: A homogeneous material with a random, liquid-like molecular structure.
  • Ceramic is a hard, unreactive material that can withstand high temperatures, made by baking clay in a kiln; ceramics are non-conductors.
  • A "composite" material is when two or more different materials are combined together to create a superior and unique material.

SPM Form 4: Periodic Table of elements (Checklist)

periodic table of elements
  • Periodic Table: the table showing the elements in order of increasing proton number; similar elements are arranged in columns called groups.
  • Group: A vertical column of elements in the Periodic table.
  • Period: A horizontal row of the Periodic Table; its number tells you how many electron shells there are.
  • Alkali metals: the Group I elements of the Periodic Table, which include lithium, sodium, potassium, rubidium, caesium and francium.
  • Alkaline earth metals: the Group II elements of the Periodic Table, which include beryllium, magnesium, calcium, strontium, barium, and radium.
  • Halogens: the Group VII elements of the Periodic Table, which include fluorine, chlorine, bromine, iodine and astatine.
  • Noble gases: the Group 18 elements of the Periodic Table; they are called ‘noble’ or inert gases because they are so unreactive, which include helium, neon, argon, krypton, xenon and radon.
  • Transition elements: the elements in the wide middle block of the Periodic Table (elements in group 3 to group 12).
  • Metal: an element that shows metallic properties (for example conducts electricity, and forms positive ions)
  • Non-metal - an element that does not show metallic properties: the non-metals lie to the right of the zig-zag line in the Periodic Table.
  • Amphoteric oxide: An oxide that exhibits both acidic and basic properties.
  • The atomic radius is a term used to describe the size of the atom.
  • The ionization energy is the energy required to completely remove an electron from a gaseous atom or ion.
  • Electron affinity reflects the ability of an atom to accept an electron. It is the energy change that occurs when an electron is added to a gaseous atom.
  • Electronegativity is a measure of the attraction of an atom for the electrons in a chemical bond. The higher the electronegativity of an atom, the greater its attraction for bonding electrons.