Reaction of Alkali Metals with Water

Alkali metals are more reactive in their reactions with water when going down the group. Group 1 elements react with water to form an alkaline metal hydroxide solution and hydrogen gas, H2.
  • Lithium melts and moves slowly at random on the surface of water with plenty of fizz. A colorless solution that turns red litmus paper blue is formed. 
            2Li (s) + 2H2O (l) → 2LiOH (aq) + H2 (g)
  • Sodium melts and moves rapidly at random on the surface of water with a hissing sound. A colorless solution that turns red litmus paper blue is formed. 
2Na (s) + 2H2O (l) → 2LiOH (aq) + H2 (g)
  • Potassium melts moves very fast at random on the surface of water and ignites with a lilac flame, with ‘pop’ and hissing sounds. A colorless solution that turns red litmus paper blue is formed. 
2K (s) + 2H2O (l) → 2KOH (aq) + H2 (g)

The arrangement of the Group 1 elements in ascending order of their reactivity is lithium, sodium and potassium.