Sodium, magnesium and
aluminium have giant metallic structures with strong metallic bonds. They have
relatively high melting point. Silicon has a giant covalent structure with
strong covalent bonds. This accounts for its exceptionally high melting point.
The rest are simple molecules with weak intermolecular van der Waals forces.
The strength of the van der Waals force and the melting point increases in the
order: Ar ˂ Cl2 ˂ P4 ˂ S8. Sodium, magnesium
and aluminium have mobile electrons. They are conductors. Silicon is a
metalloid. The energy gap between the conduction band and the valence bond is
small. It is a semi-conductor. Phosphorous, sulphur, chlorine and argon do not
have mobile electrons. They are non-conductors.
STPM Chemistry Syllabus 2nd Term
Chapter 7: Chemical
Energetics
7.1 Enthalpy changes of
reaction, ΔH
7.2 Hess’ law
7.3 Born-Haber cycle
7.4 The solubility of solids
in liquids
Chapter 8: Electrochemistry
8.1 Half-cell and redox
equations
8.2 Standard electrode
potential
8.3 Non-standard cell
potentials
8.4 Fuel cells
8.5 Electrolysis
8.6 Applications of
electrochemistry
Chapter 9: Periodic Table:
Periodicity
9.1 Physical properties of
elements of Period 2 and Period 3
9.2 Reactions of Period 3 elements
with oxygen and water
9.3 Acidic and basic
properties of oxides and hydrolysis of oxides
Chapter 10: Group 2
10.1 Selected Group 2
elements and their compounds
10.2 Anomalous behavior of
beryllium
10.3 Uses of Group 2
Chapter 11: Group 14
11.1 Physical properties of
Group 14 elements
11.2 Tetrachlorides and
oxides of Group 14 elements
11.3 Relative stability of
+2 and +4 oxidation states of Group 14 elements
11.4 Silicon, silicone and
silicates
11.5 Tin alloys
Chapter 12: Group 17
12.1 Physical properties of
selected Group 17 elements
12.2 Reactions of selected
Group 17 elements
12.3 Reactions of selected
halide ions
12.4 Industrial applications
of halogens and their compounds
Chapter 13: Transition
elements
13.1 Physical properties of
first row transition elements
13.2 Chemical properties of
first row transition elements
13.3 Nomenclature and
bonding of complexes
13.4 Uses of first row
transition elements and their compounds
