Rules for figuring out oxidation numbers

  • Atoms in elemental form have an oxidation number of zero.
  • Single-atom (monoatomic) ions have an oxidation number equal to their charge.
  • In a neutral compound, oxidation numbers add up to zero. In a charged compound, oxidation numbers add up to the compound’s charge.
  • In compounds, oxygen usually has an oxidation number of –2, in which its oxidation number is –1.
  • In compounds, hydrogen has an oxidation number of +1 when it bonds to nonmetals and an oxidation number of –1 when it bonds to metals.
  • In compounds

Group 1 atoms (alkali metals) have oxidation number +1.
Group 2 atoms (alkaline earth metals) have oxidation number +2.
Group 3 atoms have oxidation number +3.
Group 17 atoms (halogens) usually have oxidation number –1.